Explain Carnot Engine!?
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IT IS THEORETICAL THERMODYNAMIC CYCLE..
- IT WAS GIVEN LEONARD CARNOT.
- IT GIVES THE MAXIMUM POSSIBLE EFFICIENCY HEAT ENERGY.
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EXPLANATION.
Carnot cycle :
(1) = It is a cyclic process which involves four steps,
(2) = The engine based on Carnot cycle is called Carnot engine Or four steps engine.
(3) = The efficiency of Carnot engine is maximum but not 100%.
The four steps involved in the Carnot cycle are as follows :
Stoke = 1.
Isothermal reversible expansion of ideal gases.
Stoke = 2.
Adiabatic reversible expansion of ideal gases.
Stoke = 3.
Isothermal reversible compression of ideal gases.
Stoke = 4.
Adiabatic reversible compression of ideal gases.
T₁ = Lower temperature = Temperature of sink.
T₂ = Higher temperature = temperature of source.
T₃ = Heat rejected by a cycle at T₁.
T₄ = Heat absorbed by cycle at T₂.
The efficiency of Carnot engine can be 100%.
If temperature of sink becomes to 0 kelvin or temperature of source becomes to ∞. but both are not possible so efficiency can never be 100%.
The efficiency can be increased by decreasing temperature of sink or by increasing temperature of source or both.
STATEMENT.
(1) = If temperature of sink decreases by ΔT or temperature of source increases by same ΔT then decreasing of temperature of sink is more efficient.
(2) = Any heat engine operating in reversible cycle between two temperature [ T₁ & T₂ will have the same efficiency ].
(3) = The efficiency of heat engine operating on reversible cycle is greater than that operating on irreversible cycle between the same two temperatures.
(4) = The efficiency of any Carnot cycle is independent from nature of fluid used.
Equations :
Isothermal expansion [ A → B ].
⇒ W₁ = Q₁ = μRT₁㏑(v₂/v₁).
Adiabatic expansion [ B → C].
⇒ W₂ = μR/(γ - 1) (T₁ - T₂).
Isothermal compression [ C → D ].
⇒ Q₂ = W₃ = μRT₂㏑(v₄/v₃) = Q₂ = μRT₂㏑(v₄/v₃).
Adiabatic compression [ D → A ].
⇒ W₄ = μR/(γ - 1) (T₂ - T₁).
The cycle of operations is called Carnot cycle.
In first two steps work is done by engine W₁ and W₂ are positive.
In last two steps work is done on gas.
W₃ and W₄ are negative.
The work done in complete cycle W = The area of the closed part of the p-v cycle.
⇒ W = W₁ + W₂ + W₃ + W₄.
Efficiency of Carnot engine,
⇒ η = W/Q₁ = μRT₁㏑(v₂/v₁) + μRT₂㏑(v₄/v₃) / μRT₁㏑(v₂/v₁).
B to C and D to A are adiabatic paths.
So,
⇒ v₂/v₁ = v₃/v₄.
⇒ η = T₁ - T₂/T₁ = Q₁ - Q₂/Q₁.
⇒ η = 1 - Q₂/Q₁ = 1 - T₂/T₁.
⇒ Q₁/T₁ = Q₂/T₂
⇒ η = T₁ - T₂/T₁ x 100%.
⇒ η = Q₁ - Q₂/Q₁ x 100%.
CARNOT THEOREAM.
No irreversible engine (I) can have efficiency greater than Carnot reversible engine (R) working between same hot and cold reservoirs.
η(r) = η(i).
⇒ 1 - T₂/T₁ > 1 - Q₂/Q₁.