explain Corey's house synthesise with equation and example
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The Corey-House synthesis process is the reaction between the organocopper reagent, usually a lithium dialkylcuprate as prepared above, and a second alkyl (pseudo)halide or an aryl iodide. This results in the formation of a C–C bond between the two organic fragments: Li+[R–Cu–R]– + R'–X → R–R' + "RCu" + LiX.
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The Corey–House synthesis (also called the Corey–Posner–Whitesides–House reaction and other permutations) is an organic reaction that involves the reaction of a lithium diorganylcuprate (R2CuLi) with an organyl (pseudo)halide (R'X) to form a new alkane, as well as an ill-defined organocopper species and lithium halide as byproducts.[1][2][3]
Li+[R–Cu–R]– + R'–X → R–R' + "RCu" + Li+X–
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