Explain electrical properties of solid on the basis of band theory.
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Answer:
Depending upon the electrical conductivities the solids are classified in given three types:-
Conductors:-
The solids which have the conductivity in range 104 to 107 ohm-1 are called the conductors metals are called the best conductors of electricity.
Insulators:-
The solids which have extremely low conductivities ranging between 10-20 to 10-10 ohm are called insulators.
Example: Plastics, Wood, Rubber etc.
Semiconductors:-
The solids which have conductivity in between those of conductors and insulators are called the semiconductors.
Example: Silicon, Germanium etc
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On the basis of band theory the solid can be conductors, insulator or semiconductor.
- Conductors conduct electricity electrics through the movement of electrons (metals) or ions (electrolytes).
- The atomic orbitals of metals form molecular orbitals that is so close in energy which is form bonds.
- In semiconductor, the gap is small. For example, silicon and germanium. Their conductivity which can be increased by adding impurity which can be electron rich or electron deficient.
- When increase in conductivity is due to the electron - rich impurity, that type of conductivity is called n-type semiconductor.
- When the increase in conductivity is due to electron-deficient impurity, it is called p-type semiconductors.
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