Question

Explain primary and secondary salt effect in solution ?

Answer 1

Primary salt effect. It has been observed that the rate of a reaction can be altered by the presence of non-reacting or inert ionic species in the solution. This effect is profound when the reaction takes place between ions, even at low concentrations.


The term “secondary kinetic salt effect'' is used to indicate a kinetic. salt effect dueto a change in concentration of the reacting molecules on. account of a change in the inter-ionic forces.1,2. Such effects are very com- monly met in the study of kinetic reactions.

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Answer 2

Answer:

Primary salt effect. It has been observed that the rate of a reaction can be altered by the presence of non-reacting or inert ionic species in the solution. This effect is profound when the reaction takes place between ions, even at low concentrations. The term “secondary kinetic salt effect'' is used to indicate a kinetic salt effect due to a change in concentration of the reacting molecules on account of a change in the inter-ionic forces. 1,2. Such effects are very commonly met in the study of kinetic reactions.

Explanation:

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