Explain the hybridisation and shape of following molecules : (i) PCI5 (i) SF6
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The hybridization of the P in PCl5 is sp3d and the hybridization of the S in SF6 is sp3d2. PCl5 has trigonal bipyramidal geometry. In this case, the axial bonds are slightly longer than the equatorial bonds. ... In this case, all the bonds have the same length since all bonds experience similar repulsion from other bonds.
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