explain why Faraday's equation is related to corrosion rate?
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Explanation:
Faraday’s law is used to compute corrosion rates according to the kinetics of the cathodic and anodic reactions or the oxidation-reduction. Based on this empirical law, a linear relationship exists between the rate of corrosion or metal dissolution and the corrosion current.
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Faraday's theory:
Faraday's theory states that, "when current produced by anodic areas are known, it is possible to calculate the rate of corrosion penetration or corresponding mass loss"
Faraday's equation:
where,
RM - Corrosion rate
Icorr - Corrosion current
M - Atomic weight of metal
p - Density
n - Charge number of electrons exchanged within dissolution reaction
F - Faraday constant (96.485 C/mol)
M/n - Equivalent weight
Principles:
- Faraday’s law is used to determine corrosion rate based on the kinetics of the cathode and anode reactions otherwise known as the oxidation-reduction process.
- The determination of the rate of corrosion requires the determination of corrosion currents. This is possible only when the reaction mechanisms which involves the corrosion reactions are also identified.
- In this case, Tafel slope analysis is used to calculate corrosion currents. Based on this, the Tafel plot is used in the performance analyzing the currents.
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