Chemistry, asked by spandanasathish474, 6 months ago

Find the empirical formula of the compound which contains 33.18 percent of carbon 4.60 percent of hydrogen 29.49 percent of Oxygen and 32.72 percentage of chlorine respectively.

Answers

Answered by mayurkodange14
0

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Explanation:

The empirical formula of a compound is, C_3H_5O_2ClC

3

H

5

O

2

Cl

Solution :

If percentage are given then we are taking total mass is 100 grams.

So, the mass of each element is equal to the percentage given.

Mass of C = 33.18 g

Mass of H = 4.60 g

Mass of O = 29.49 g

Mass of Cl = 32.72 g

Molar mass of C = 12 g/mole

Molar mass of H = 1 g/mole

Molar mass of O = 16 g/mole

Molar mass of Cl = 35.5 g/mole

Step 1 : convert given masses into moles.

Moles of C = \frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{33.18g}{12g/mole}=2.765moles

molar mass of C

given mass of C

=

12g/mole

33.18g

=2.765moles

Moles of H = \frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{4.60g}{1g/mole}=4.60moles

molar mass of H

given mass of H

=

1g/mole

4.60g

=4.60moles

Moles of O = \frac{\text{ given mass of O}}{\text{ molar mass of O}}= \frac{29.49g}{16g/mole}=1.843moles

molar mass of O

given mass of O

=

16g/mole

29.49g

=1.843moles

Moles of Cl = \frac{\text{ given mass of Cl}}{\text{ molar mass of Cl}}= \frac{32.72g}{35.5g/mole}=0.9217moles

molar mass of Cl

given mass of Cl

=

35.5g/mole

32.72g

=0.9217moles

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C = \frac{2.765}{0.9217}=2.99\approx 3

0.9217

2.765

=2.99≈3

For H = \frac{4.60}{0.9217}=4.99\approx 5

0.9217

4.60

=4.99≈5

For O = \frac{1.843}{0.9217}=1.99\approx 2

0.9217

1.843

=1.99≈2

For Cl = \frac{0.9217}{0.9217}=1

0.9217

0.9217

=1

The ratio of C : H : O : Cl = 3 : 5 : 2 : 1

The mole ratio of the element is represented by subscripts in empirical formula.

The Empirical formula = C_3H_5O_2Cl_1=C_3H_5O_2ClC

3

H

5

O

2

Cl

1

=C

3

H

5

O

2

Cl

Therefore, the empirical of the compound is, C_3H_5O_2ClC

3

H

5

O

2

Cl

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