For a given gas at 1 atm pressure, rms speed of the molecules is 200 m/s at 127ºC. At 2 atm pressure and at 227ºC, the rms speed of the molecules will be:
(A) 80 m/s (B) 80√5 m/s
(C) 100 m/s (D) 100√5 m/s
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Given :
The rms speed of the gas at 1 atm and 400 K ( 127 °C ) = 200 m/s
To find :
The rms speed of the gas at 2 atm and 500 K ( 227 °C ) .
Solution :
let rms speed at 500 K is v .
rms speed , v = √( 3 * R * T / M )
Now , at 1 atm and 400 K ,
200 = √( 3 * R * 400 / M ) .....(i)
at 2 atm and 500 K ,
v = √( 3 * R * 500 / M ) ......(ii)
dividing (ii) by (i) ,
v / 200 = √ ( 500 / 400 )
=> v = ( 200 * √5 ) / 2
=> v = 100√5 m/s
The rms speed of the gas at 2 atm and 500 K ( 227 °C ) is 100√5 m/s .
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