for a reaction A+B 2C+2D ,kp=1.2×10th the power 3 kpa at 450k. calculate the value of ke in mol/lit
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Kp and Kc are the gas constant of a gaseous mixture. Where Kp is the molar concentrations and Kc is the partial pressure of a gas inside a closed system.
For the given reaction,
A+B---2C+2D
given,
Kp=1.2×10³ k Pa
Kp=1.2×10³×10³Pa
=1.2×10⁶Pa=1.2×10⁶×9.869×10⁻⁶atm
=11.8atm
and the temperature,T= 450 k
R=0.08206 L atm/mol k
Here, Δn=n₂-n₁=4-2=2
Relation between Kp and Kc is,
Kp=Kc(RT)Δn
⇒11.8=Kc(0.08206×450)²
⇒11.8=Kc(86.927)²
⇒Kc≅0.009mol/L
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