For Five mark
Derive the ideal gas equation and explain following terms:-
(a) Compressibility factor.
(b) Critical temperature.
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Answer:
a) Z = P × V / n × R × T , where Z is the compressibility factor, for pressure P , volume V , gas constant R , number of moles n , and temperature T .
a) the compressibility factor (Z) is a correction factor which describes the deviation of a real gas from ideal gas behaviour.
b) For an ideal gas a = 0, since there exist no forces of attraction between the molecules. Therefore, the TC of such gases equal to zero.
Tc=27Rb8a
b) the temperature of a gas in its critical state, above which it cannot be liquefied by pressure alone.
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