For the reaction, 2NO2 (g)======2NO (g) + O2(g), Kc = 1.8 × 10^6 at 185°C. At 185°C, the value of Kc for the reaction - NO(g) + 1/2 O2(g)====== NO2(g) is -.
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For reaction,
2NO2 ====== 2NO + O2
[ Kc = 1.8 × 10^6 ] ----(1)
Kc for eq. (2) = Kc'
NO + 1/2O2 ===== NO2
--------(2)
Reaction (2) is the reverse reaction of reaction (1) and divided by 1/2, hence
Kc' = 1/Kc
Kc' = √(1/ Kc)
Kc' = √( 1/ 1.8×10^6 )
Kc' = 0.76 × 10^-6
Kc' = 7.6 × 10^-7
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