Ge, S and Br belong to the groups 14, 16 and 17 respectively. Predict the empirical
formulae of the compounds those can be formed by: (i) Ge and S, (ii) Ge and Br.
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(a) B and C will form a covalent compound since both are non-metals.
(b) A and C will form an ionic compound since A is alkali metal and C is non-metal.
C.S. Weinert, in Comprehensive Organometallic Chemistry III, 2007
3.13.6.1.2 Compounds with germanium bonded to sulfur, selenium, or tellurium
Germanium compounds containing dithiocarbonate179 and dithiophosphate180,181 ligands which have Ge–S bonds have been prepared and structurally characterized.
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