Give the advantages of organolithium compounds over organomagnesium compounds?
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Organolithium compounds behave very much like Grignard reagents, but with increased reactivity. They offer advantages over the magnesium compounds when the group or the carbonyl compound is highly branched. ... The result is that the compound becomes an enolate salt.
The most important synthetic use of Grignard reagents and organolithium reagents is to form new carbon-carbon bonds by addition to polar multiple bonds, particularly carbonyl bonds. An example is the addition of methyl-magnesium iodide to methanal:
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