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On dissolving 6 gm of metal in Sulphuric acid, 13.53 g of the metal sulphate was formed. The specific heat of metal is 0.057 cal/g What is equivalent mass of metal, valency and exact atomic mass?

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Answered by sharanyalanka7
35

Answer:

Explanation:

Solution :-

Let us assume the chemical reaction as :-

Metal+H_2SO_4\rightarrow M_2(SO_4)_x+H_2

1) Equivalence mass of Metal = \sf\dfrac{Mass\:of\:Metal}{Mass\:of\:sulphate}\times equivalent\:mass\:of\:sulphate

Equivalence mass = \sf\dfrac{Molar\:mass}{Replacable\:hydrogen\:ions(basicity)}

Molar mass of SO_4 = 32+4(16)

= 32+64

= 96g

Number of replacable Hydrogen Ions = 2.

Equivalence mass of  sulphate = \dfrac{96g}{2} = 48g

Given , Mass of Metal = 6gm

Mass of Sulphate = Mass metal sulphate - Mass of metal in sulphuric Acid

= 13.53g - 6g

= 7.53g

Equivalent mass of metal = \sf\dfrac{6}{7.53}\times 48  = 0.796\times48

= 38.24 g

2) Valency :-

Valency = \sf\dfrac{Approx\:atomic\:mass}{equivalent\:mass}

Approx atomic mass = \sf\dfrac{6.4}{Specific\:heat}

Given specific heat = 0.057 cal/g

Approx atomic mass = \sf\dfrac{6.4}{0.057}

= 112.28g

Valency = \sf\dfrac{112.28}{38.24}

= 2.9

≈ 3

Valency = 3

3) Exact atomic mass :-

Exact atomic mass = valency\sf\timesEquivalent Mass

= 3\times 38.24

= 114.72g.

Answered by BrainlyUnnati
29

Answer:

QuestioN :

On dissolving 6 gm of metal in Sulphuric acid, 13.53 g of the metal sulphate was formed. The specific heat of metal is 0.057 cal/g What is equivalent mass of metal, valency and exact atomic mass?

GiveN :

  • Dissolving 6 gm of metal in Sulphuric acid, 13.53 g of the metal sulphate was formed.
  • The specific heat of metal is 0.057 cal/g

To FiNd :

  • The equivalent mass of metal, valency and exact atomic mass?

ANswer :

The equivalent mass of metal, valency and exact atomic mass is 114.72.

SolutioN :

\sf Equivalent\: mass\:of\:sulphate= \dfrac{\:ionic\:mass}{Valency}

\sf=\dfrac{96}{2}=48

\sf Eq.weight\:of\:metal=\dfrac{Mass\:of\:Metal}{Mass \:of \:Sulphate} \times \:48

\sf= \dfrac{6}{13.53-6}\times48

\sf=\dfrac{6}{7.53}\times48

\sf = 38.24g

\sf Approximate\:atomic\:mass=\dfrac{6.4}{Specific\:\:Heat}

\sf=\dfrac{6.4}{0.057}=112.3

\sf Valency=\dfrac{Approximate\:Atomic\:Mass}{Equivalent\:Mass}

\sf = \dfrac{112.3}{38.24}=2.9=3

\sf \implies Exact \:atomic\: mass = 3 \times 38.24 = 114.72

∴ Hence, The equivalent mass of metal, valency and exact atomic mass is 114.72.

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