HF has low volatility among hydrogen halides because
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The most volatile compound is HCl.The volatility of compound is its property to have high vapour pressure at ordinary temperature.
The order is HCl<HBr<HI<HF
HF due to hydrogen bonding is least volatile. As the molecular weight increases the intermolecular force increses due to which vander waal force of attraction also increases.Thus HI is liquid and Hcl is a gas.But due to hydrogen bonding in HF it is least volatile
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