How do you determine equivalent conductance of strong electrolyte at infinite dilution ?
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The equivalent conductivity of a strong electrolyte at infinite dilution is equal to the sum of the equivalent conductivities of the anions and cations.
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The equivalent conductance of S.E (strong electrolyte) is determined by Kohlrausch’s law at infinite dilution.
Explanation:
- When the dilution increases and reaches infinity (i.e., infinite dilution), the electrolytes dissociates completelyinto ions, and the degree of dissociation beomes unity.
- For strong electrolytes, at infinite dilution the equivalent conductance is determined by Kohlrauch's law.
- It states that at ∞ dilution, the equivalent conductance is equal to the sum of individual eq. conductance of the anions and cations.
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