How to calculate molar conductivity at infinite dilution?
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Molar conductivity is defined as the conductivity of an electrolyte solution divided by the molar concentration of the electrolyte, and so measures the efficiency with which a given electrolyte conducts electricity in solution.
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Ostwald's law of dilution, which gives the dissociation constant of a weak electrolyte as a function of concentration, can be written in terms of molar conductivity. Thus, the pKa values of acids can be calculated by measuring the molar conductivity and extrapolating to zero concentration.
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