i.
Identify the strongest acid amongst the following:
(a) Chloroacetic acid
(b) Acetic acid.
(c) Trichloroacetic acid
(d) Dichloroacetic acid
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Answer:
The increase in the acid strength of an acid depends on the number of electron with drawing groups. Greater the number of electron withdrawing groups, greater is the strength of acid.
Thus,
Trichloroacetic acid
Cl
3
C−COOH
>
Dichloroacetic acid
Cl
2
CH−COOH
>
chloroacetic acid
ClCH
2
−COOH
>
Acetic acid
CH
3
COOH
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