Identify the reagent from the following list which can easily
distinguish between 1-butyne and 2-butyne
(a) bromine, CCl₄
(b) H₂, Lindlar catalyst
(c) dilute H₂SO₄, HgSO₄
(d) ammonical Cu₂Cl₂ solution
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Answer:
(d) ammonical Cu₂Cl₂ solution
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Reagent from the above list which can easily distinguish between 1-butyne and 2-butyne is :
• We have two compounds with same number of carbon in their parent chain.
• The difference is the position of triple bond in both of them.
• One is having triple bond at terminal carbon and other is having it in between the compound.
• So for distinguishing terminal alkyne group, we use ammonical Cu₂Cl₂ solution.
• When 1-butyne react with ammonical Cu₂Cl₂ solution, it gives red ppt of copper-1-butynide.
• Hence correct option is (d)
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