If 250 g of water at 285 K is mixed with 80 g of ice at –150C. Calculate the final
temperature and composition of mixture.
[Given –
Heat capacity of ice - 0.5 cal/g-K
Heat capacity of water - 1 cal/g-K
Heat of fusion - 334 J/g
And latent heat of vaporization = 2260 J/g]
Answers
Answer:
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Given info : If 250 g of water at 285 K is mixed with 80 g of ice at –150°C.]
To find : the final temperature and the composition of mixture are ...
solution : 250g of water is at 285K or (285 - 273) = 12°C
if water loses its heat at 0°C ,
heat , Q₁ = msΔT = 250g × 1 cal/g/°C × 12°C = 3000 cal
if ice increase its temperature upto 0°C,
heat needed, Q₂ = m's'ΔT' = 80g × 0.5 cal/g/°C × 150°C = 6000 cal
here it is clear that Q₁ < Q₂
it means, the final temperature of mixture would be 0°C.
energy lost by water to convert into ice, Q₃ = mLf = 250g × 80 cal/g = 20000 cal
Q₁ + Q₃ > Q₂ , it means some part of water converted into ice and some remained in its form.
let x g of water is converted into ice.
Q₁ + x g × 80 cal/g = Q₂
⇒ 3000 cal + 80x = 6000 cal
⇒ 80x = 3000
⇒ x = 37.5g
therefore the composition of mixture ;
ice = 80g + 37.5 g = 117.5 g
water = 250 - 37.5 = 212.5 g