If a zero order reaction completed to 60% in 30 minutes then time in which reaction completed to 80% will be
Answers
Given:
The time taken for zero order reaction to complete 60%, t = 30 minutes
To Find:
The time in which reaction will be completed to 80%.
Calculation:
- After 60% completion, amount left, [R] = 40% of [R]₀ = 0.4 [R]₀
- For zero order reaction:
k = ([R]₀ - [R])/t
⇒ k = ([R]₀ - 0.4 [R]₀)/ 30
⇒ k = 0.6 [R]₀/ 30
⇒ k = 0.02 [R]₀
- Now, when reaction is 80% complete, amount left, [R] = 20% of [R]₀ = 0.2 [R]₀
- Again using the same formula, we get:
k = ([R]₀ - 0.2 [R]₀)/ T
⇒ 0.02 [R]₀ = 0.8 [R]₀/ T
⇒ T = 0.8 /0.02
⇒ T = 40 minutes
- So, the time in which reaction will be completed to 80% is 40 minutes.
Time of 80% completion = 40 minutes
Explanation:
Given: A zero order reaction completed to 60% in 30 minutes.
Find: Time in which 80% reaction is completed.
Solution:
Let the concentration of the reactant initially be x.
Then 60% reaction can be written as: 0.6x = -k *t1 ------(1)
Then 80% reaction can be written as: 0.8x = -k *t2 ------(2)
Dividing (1) by (2), we get:
0.6x / 0.8x = -k *t1 / -k *t2
3/4 = t1/t2
3/4 = 30/ t2
Therefore t2 = 4 * 30 / 3 = 40 minutes