If freezing point of water is depressed by
0.37°C in a 0.01 molal NaCl solution then freezing
point of 0.02 molal solution of urea is depressed by
0.37°C
O 0.74°C
O 0.185°C
O 0.57°C
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Answer:
As we know that,
Δtf=ikfm
where, Δtf = depression in freezing point
i=van't - Hoff factor
m=molarity
and kf=freezing point depression constant.
For 0.01 molal NaCl solution
0.37=2×kf×0.01
∴kf=2×0.010.37....(i)
For 0.02 molal urea solution
Δtf=1×kf×0.02
∴kf=0.02Δtf...(ii)
From Eqs (i) and (ii)
2×0.010.37=0.02Δtf
Δtf=2×0.010.37×0.02
∴tf=0.37
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