Iit question mate solve .......
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See attachment mate .........
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The above cell reaction is as follows,
Zn(s) + Ni2+(aq) ⇌ Zn2+(aq)+ Ni(s)
Cell can be represented as,
Zn(s) | Zn2+(aq) || Ni2+(aq) | Ni(s)
Given, Standard Cell Potentials,
E0Zn | Zn2+ = -0.75V
& E0Ni2+ | Ni = -0.24V
E0cell = E0cathode - E0anode
= 0.75 - 0.24 = 0.51V
can be written as,
From the cell reaction depicted above,
Zn(s) + Ni2+(aq) ⇌ Zn2+(aq)+ Ni(s)
1 - x x
keq = [Zn2+] / [Ni2+]
= x / (1-x)
Hence, concentration of Ni2+ in solution at equilibrium, [Ni2+] = 1 / 1.78 x 1017 = 5.6 x 10-8 M
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