In a distillation process for separating methanol from ethanol, methanol being the more
volatile component, the weight percent of methanol in top product is
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Purified methanol is produced by distilling a water methanol mixture in (a) a first column from which is taken a product methanol stream at an upper level, weakly aqueous methanol as a side stream and water as bottoms and (b) a second column in which that weakly aqueous methanol is separated into an overhead product stream and aqueous methanol bottoms. The first column may be preceded by a preliminary volatiles-removal column. The process is economical in heat consumption, especially when methanol vapor from the second column is heat-exchanged with the feed or bottoms of the first column.
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