In an irreversible process taking place at constant t and p and in which only pressure-volume work is being done the change in gibbs free energy (dg) and change in entropy (ds) satisfy the criteria:
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An irreversible process
⇒ Spontaneous process
⇒(dS)V,E(change in entropy) =+ve>0
⇒(dG)T,P (change in Gibbs free energy) =−ve<0
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