In general, for a diprotic acid, Ka1 >> Ka2. This is reasonable because chose one: (1()Ka1 xKa2 = K for the combined equilibrium. (2)Diprotic acids have 2 protons to donate (3) It is more difficult to remove a proton from the -1 ion that it is from the neutral acid. (4)Ka1 corresponds to a strong acid while Ka2 corresponds to a weak acid. (5)None of the above is correct
Answers
For a general diprotic acid , Ka1 >> Ka2 because of the following reason:
- It is more difficult to remove a proton from -1 ion than a neutral acid.
Let us consider a diprotic acid AH2.
The proton (H+) can be easily released from the neutral acid (AH2) . However , a uni-negative ion or conjugate base (AH-) doesn't allow the release of another proton very easily.
Hope It Helps.
Explanation:
For a general diprotic acid , Ka1 >> Ka2 because of the following reason:
It is more difficult to remove a proton from -1 ion than a neutral acid.
Let us consider a diprotic acid AH2.
\sf{AH_{2} \overset{ka_{1}}\longrightarrow \: A{H}^{ - } + {H }^{ + } }AH
2
⟶
ka
1
AH
−
+H
+
\sf{A{H}^{ - } \overset{ka_{2}}\longrightarrow \: {A}^{ - } + {H }^{ + } }AH
−
⟶
ka
2
A
−
+H
+
\boxed{ \sf{ \red{ \huge{ka_{1} > > ka_{2}}}}}
ka
1
>>ka
2
The proton (H+) can be easily released from the neutral acid (AH2) . However , a uni-negative ion or conjugate base (AH-) doesn't allow the release of another proton very easily.
Hope It Helps.