Question

In normal reaction conditions, chlorobenzene does not react with NaOH, but 1-

chloro-4-nitrobenzene reacts with NaOH in these conditions. Explain.​

Answer 1

Explanation:

If we compare the structures of chloro-benzene and 1-chloro-4-nitrobenzene then in one structure there is presence of nitro group (-NO_2)(−NO

2) which is very strong electron withdrawing activates the ring for the nucleophilic attack

When the reaction with chloro-4-nitrobenzene occurs, SNAr mechanism takes place, because Meisenheimer's intermediate is stabilized by resonance

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