In polarography, DME is used as ____ electrode.
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Answer:
Mercury has been widely used in electrochemistry, especially as a working electrode
Explanation:
A major advantage of the DME is that each drop has a smooth and uncontaminated surface free from any adsorbed analyte or impurity. The self-renewing electrode does not need to be cleaned or polished like a solid electrode. This advantage comes at the cost of a working electrode with a constantly changing surface area.
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In polarography, DME is used as a working electrode.
- DME stands for dropping mercury electrode.
- In this electrode, mercury is the main constituent because it can be renewed after each drop of its usage as mercury is liquid.
- The surface remains contamination-free and pure, unlike solid electrodes. Polarography is widely used in industries and laboratories to measure chemical equilibria, rate of reaction and structure of organic compounds.
- In this polarography, KCL is generally used as an electrolyte while mercury act as a counter electrode because it can act as both inside and cathode.
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