Intramolecular hydrogen bonding takes place in ortho-nitrophenol but not in para-nitrophenol
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The above pic shows their structures that I posted in another question. The hydrogen bond doesn't happen within the molecule on para position due to larger distance between the two groups than in ortho position.
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In intermolecular in ortho nitrophenol the hydrogen bond is near and in para it is opposite. So it doesn't occurs.
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