Iron oxide has formula Fe 0.940. What fraction of Fe exists as Fe +3?
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Solution :
Let there are 100 oxide ions and 94 iron ions.
Fe+x:O−2 Total negative charge on 100 oxide ions =-200
=94 :100
It means as per the concept of charge neutrality , 94 iron ions should have total charge of +200
let number of Fe+3=x
∴ Number of Fe+2 =(94-x)
Total positive charge =3x-2(94-x)=200
On solving , x =12
%Fe+3=1294×100 =12.8%
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