It is been said that in case of natural rubber there is formation of cis structure which doesn't enable chains to come closer but my question is that how it doesn't allow ...if it doesn't allow then what happens in trans case?...if it allows then how and if it doesn't then why?
Please don't write silly answers if you know then answer or else ur answer is going to vanish
Answers
Answer:
Polyisoprene, polymer of isoprene (C5H8) that is the primary chemical constituent of natural rubber, of the naturally occurring resins balata and gutta-percha, and of the synthetic equivalents of these materials. Depending on its molecular structure, polyisoprene can be a resilient, elastic polymer (elastomer), as in the case of natural rubber and isoprene rubber, or a tough, leathery resin, as in the case of natural and synthetic balata or gutta-percha
The chemical structure of isoprene can be represented as CH2=C(CH3)—CH=CH2. Polyisoprene—built up from the linking of multiple isoprene molecules—can assume any one of four spatial configurations, or isomers, each of which imparts a unique set of properties to the polymers. As the repeating units of polyisoprene, the four isomers have the following structures:
Molecular structures.
Of these four isomers, the most important are the cis-1,4 polymer and the trans-1,4 polymer.
Cis-1,4 Polyisoprene
Natural rubber consists almost exclusively of the cis-1,4 polymer, which is produced in the milky latex of certain plants—most notably the rubber tree (Hevea brasiliensis). The uniqueness of natural rubber lies in its physical properties of extensibility and toughness, summarized by its ability to be stretched repeatedly to seven or eight times its original length. In the absence of tensile (stretching) stress, the polymer chains assume an amorphous, or disordered, arrangement. On being stretched, however, the molecules readily align into an ordered crystalline arrangement. Crystallinity lends greater strength to the material, so natural rubber is considered to be “self-reinforcing.” In its natural state, however, natural rubber is greatly affected by temperature: it crystallizes on cooling, taking only several hours to do so at −25 °C (−13 °F), and it becomes tacky and inelastic above 50 °C (120 °F). In addition, it is swollen and weakened by hydrocarbon oils, and it reacts with oxygen and ozone in the atmosphere, leading to rupture of the polymer molecules at the carbon-carbon double bonds and softening and cracking of the material over time. These disadvantages are overcome to a great extent by cross-linking the polymer chains through the process known as vulcanization.
Isoprene rubber (IR) is manufactured by the polymerization of synthetic isoprene, which is obtained from the thermal cracking of the naphtha fraction of petroleum. Polymerization is conducted in solution, using both anionic and Ziegler-Natta catalysts. The product is at most 98 percent cis-1,4 polyisoprene, and its structure is not as regular as natural rubber in other respects. As a result, it does not crystallize as readily as the natural material, and it is not as strong or as tacky in the raw (unvulcanized) state. In all other respects, though, isoprene rubber is a complete substitute for natural rubber. For both materials, the principal usage is in tires, although these elastomers are also preferred for rubber springs and mountings, owing to their good fatigue resistance and high resilience. Footwear is an important application, and natural rubber is still used in adhesives (such as rubber cement).
Trans-1,4 Polyisoprene
Trans-1,4 polyisoprene is the dominant isomer in gutta-percha and balata, two materials that, like natural rubber, are derived from the milky exudate of certain trees. Unlike the cis-1,4 polymer, however, the trans-1,4 polymer is highly crystalline, so balata and gutta-percha are tough, hard, and leathery materials—properties that led in the 19th century to their use as sheathings for underwater cables and golf balls. The trans-1,4 polymer can also be synthesized with Ziegler-Natta catalysts, yielding a synthetic balata of similar properties that also is employed in golf-ball covers as well as in orthopedic devices such as splints and braces.
Explanation:
It doesn't allow because of repulsion between molecules of CH2 on the same side(cis) and It can get change into 1,2polymer
the trans polymer can change into 3,4polymer.
Just I written the explanation which I know... I have to think more about its correctness... almost I think my answer is right
thank you
Explanation:
So, basically your question is quite interesting.
I am trying to make you understand in simple words but can't assure that you will definitely understand or I will definitely make you understand.
So, coming to the question.
It's been said that in case of natural rubber there is formation of cis structure which doesn't enable chains to come closer.
Reason for this may be defined as :
- Cis structure has both the groups attached on same side.
- Take the example of your hands.
- Let, you put your both hands straight forward.
- Do you think that it will be easy for anyone to tackle you while your both hand are on same side in front ??
- If you are able to think what I am saying, you will get your own answer.
Now, coming to the case of trans structure.
- In case of trans structure, the groups are attached on the opposite sides.
- So, again take the examples of your hands.
- Let one hand is strerched towards front and another in backwards direction.
- It is quite obvious that you will be tackled down by anyone easily as you have only one hand to save yourself in ine direction.
So, same thing happens in case of the above mentioned conditions.
Hope you got your answers. !!