Iupac name of sodium nitroprusside in coordination chemistry
Answers
Answer:
✍️For nomenclature purposes, any form of NO bound to a metal is always treated as a neutral three electron donor and is always termed nitrosyl. This is because IUPAC wants rules that can be applied blindly without having to perform complicated experiments to determine how exactly the ligand is bound. And we shall see in a second that it is very non-trivial.
✍️Considering that and checking the [Fe(CN)5NO]2− fragment, we take away 5 CN− leaving us with [Fe(…)NO]3+ which indicates that the correct IUPAC name for sodium nitroprusside is sodium pentacyanidonitrosylferrate(III). (Not (II).)
✍️The product formed would be, by the same approach, sodium pentacyanidonitrosylsulfidoferrate(III). But we’ll come back to that.
✔️Hope it will be helpful.✔️
Answer:
Explanation:
Sodium pentacyanonitrosylferrate(II)