Question

K3[Al(C2O4)3] IUPAC name of the following compound

Answer 1

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The IUPAC name for K3 [Al (C2O4)3] is ☆POTASSIUM TRIOXALATOALUMINATE☆

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Answer 2

IUPAC name of $K_3[Al(C_2O_4)_3]$ is potassium trioxalato aluminate (III)

Explanation:

Rules for naming of the coordination compounds :

1. The ligand named first then metal.

2. The charge of metal indicated with the Roman numerals and enclosed in the parenthesis after metal name.

3. The ligands are named in alphabetical order before the metal ion.

4. Ligands that include a numerical prefix in the name use the prefixes bis for 2, tris for 3, or tetrakis for 4 to indicate their number.

5. If the complex ion is an anion, we drop the ending of the metal name and add –ate.

In the given coordination compound, Al is the aluminium metal, $C_2O_4$ is the ligand named as oxalato.

The charge on $[Al(C_2O_4)_3]$ is -3 and oxalate is having an oxidation state of -2.

$x+3(-2)=-3$

$x=+3$

Hence, the IUPAC name of $K_3[Al(C_2O_4)_3]$ is potassium trioxalato aluminate (III)

Learn more about naming of coordination compounds:

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