KH for H2 (g) / water system is 5.34*107 torr. If the partial pressure of H2, over a solution at 25°C is 760 torr, then determine the solubility of hydrogen.
Assume density of H2O and solutions are same
(1) 6.4 x 10-3 mol L-1
(2) 7.89 x 10-4 mol L-1
(3) 5.9 ~ 10-3 mol L-1
(4) 8.9 x 10-4 mol L-1
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Answer:
Henry's law states that :
where p = partial pressure of the gas above the solution.
is the Henry's solubility constant for the solvent & solute at given T°C
c = molar concentration of the solute in the solution in moles/Litre at given T°C
p = 1 bar and =71.18 kbar-Litre/mol
c = 1 / 71.18 * 10³ = 14.048 mol/Litre
concentration = 14.048 mol/Litre or 28.096 gms/Litre
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