Question

Markonikov addition takes for HBr not for HCl or HI

Answer 1

Answer:

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In the presence of peroxides, the addition of HBr occurs by a free-radical mechanism and the orientation is anti-Markovnikov. This is true only for HBr. Free radical addition of HF and HI has never been observed, even in the presence of peroxides, and of HCl only rarely.

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Answer 2

Answer:

Because the HBr adds on the "wrong way around " in the presence of organic peroxides, this is often known as the peroxide effect or anti-Markovnikov addition, whereas HCl and HBr or HI don not show this effect