Match the graph given in Column I with the order of reaction given in Column II.
More than one item in Column I may link to the same item of Column II. [NCERT Exemplar]
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Answer:
CHEMISTRY
Match the graphs given in column I with the order given in column II and mark the appropriate choice.
Column II
(i) Third order
(ii) First order
(iii) Zero order
(iv) Second order
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ANSWER
Formula that relate concentration and time is:-
Kt=
n−1
1
[
Ao
n−1
1
−
At
n−1
1
],
t∝
Ao
1
n−1
For zero order reaction, this equation will be
At=Ao−Kt
Y=+c−mx so the first is zero order reaction graph,
[slope is negative]
For first order reaction, this equation will be
log[At]=log[Ao]−Kt
Y=+c−mx so the second is first order reaction graph,
[slope is negative]
For C and D there is direct relation between time and concentration
t∝
Ao
1
n−1
for C power of {A} is −1 that means 1−n=−1
So order(n)=1+1=2
for D power of {A} is −2that means 1−n=−2
So order(n)=2+1=3.
So the correct option is [B].