mechanism of hoff man
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Hoffmann bromamide degradation reaction :
The Conversion of a primary amide to a primary amine containing one carbon atom less than the original amide on heating with the mixture of Br2 in the presence of NaOH or KOH.
It involves the :
CH3 CONH2 + Br2 + 4NaOH = CH3 NH2 + 2NaBr + Na2 CO3 + 2H2O
CH3CH2CONH2 + Br2 + 4NaOH = CH3CH2NH2 + 2NaBr + Na2CO3 + 2H2O
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