n mole each of H2O(g), H2(g) and O2(g) are mixed at a suitable high temperature to attain the equilibrium
2H2O(g) 2H2(g) + O2(g). If y mole of H2O(g) are the dissociated and the total pressure maintained is
P, calculate the Kp.
Answers
your question is -> n mole each of H2O, H2, O2 are taken in closed container at temperature T. if y mole of H2O are disasssociated at equillibrium and equillibrium pressure is P then calculate the value of Kp.
solution : 2H2O ⇔2H2 + O2
at t = 0, n n n
at eq. (n - y) (n + y/2) n + y
so, total no of moles = n - y + n + y/2 + n + y = 3n + y/2
now, let's derive the expression for Kp
= p(H2)² × p(O2)¹ /p(H2O)²
= {P × (n + y/2)/(3n + y/2)}² × {P × (n + y)/(3n + y/2)}¹/{P × (n - y)/(3n + y/2)}².
= P(n + y/2)² × (n + y)/(3n + y/2)(n - y)²
your question is -> n mole each of H2O, H2, O2 are taken in closed container at temperature T. if y mole of H2O are disasssociated at equillibrium and equillibrium pressure is P then calculate the value of Kp.
solution : 2H2O ⇔2H2 + O2
at t = 0, n n n
at eq. (n - y) (n + y/2) n + y
so, total no of moles = n - y + n + y/2 + n + y = 3n + y/2
now, let's derive the expression for Kp
= p(H2)² × p(O2)¹ /p(H2O)²
= {P × (n + y/2)/(3n + y/2)}² × {P × (n + y)/(3n + y/2)}¹/{P × (n - y)/(3n + y/2)}².
= P(n + y/2)² × (n + y)/(3n + y/2)(n - y)²