n2o4 is 10% dissociated at a total pressure p1 and 20% dissociated at atotal pressure p2 .then ratio p1/ p2
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N2O421−α⇔2NO202α
Kp=(nNO2)2(nN2O4)×[P∑n]1
For 33% dissociation:
Kp=(2×33)267×[P1133]1
For 50% dissociation:
Kp=(2×50)250×[P2150]1
∴P1P2=133×67×(2×50)2(2×33)2×150×50=2.72
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