Name any one rise of radicals ?
Answers
The Rise of Radicals in Bioinorganic Chemistry
Harry B Gray et al. Isr J Chem. 2016 Oct.
Free PMC article
Abstract
Prior to 1950, the consensus was that biological transformations occurred in two-electron steps, thereby avoiding the generation of free radicals. Dramatic advances in spectroscopy, biochemistry, and molecular biology have led to the realization that protein-based radicals participate in a vast array of vital biological mechanisms. Redox processes involving high-potential intermediates formed in reactions with O2 are particularly susceptible to radical formation. Clusters of tyrosine (Tyr) and tryptophan (Trp) residues have been found in many O2-reactive enzymes, raising the possibility that they play an antioxidant protective role. In blue copper proteins with plastocyanin-like domains, Tyr/Trp clusters are uncommon in the low-potential single-domain electron-transfer proteins and in the two-domain copper nitrite reductases. The two-domain muticopper oxidases, however, exhibit clusters of Tyr and Trp residues near the trinuclear copper active site where O2 is reduced. These clusters may play a protective role to ensure that reactive oxygen species are not liberated during O2 reduction.
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Answer:
Some name that led to rise of radicals:
Failure of Moderates
Economic Degradation
Ill-treatment of Indians in South America
Ideological Climate
Influence of International Events
Partition of Bengal
Explanation:
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