name the deliquescent alkali
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Sodium hydroxide NaOH
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Sodium hydroxide is a deliquescent alkali.
- Deliquescent substances are solids that tend to absorb moisture from the air and dissolve it.
- This process occurs when the vapour pressure of the solution that is formed is less compared to the partial pressure of water vapour in the air.
- For example, NaOH, KOH, FeCl3, LiCl, Cu (NO3)2, NaNO3, LiNO3 etc are deliquescent substances.
- Hygroscopic substances such as paper, cotton, caramel, fertilizer and common table salt are considered deliquescent.
- Certain hydrated crystalline salts when exposed to the atmosphere at ordinary temperature lose their water of crystallization molecules either partially or completely and become anhydrous.
- This is called efflorescence.
- This process occurs when the aqueous vapour pressure of the hydrate is greater compared to the partial pressure of the water vapour in the air.
- The efflorescent substance is a water-based chemical compound with its molecules, which, when exposed to air, lose this water through evaporation.
- Due to the affinity of deliquescent substances to atmospheric pressure, such materials may require storage in very tightly sealed containers or storage tanks.
- Several deliquescence brines from salts at elevated temperatures are corrosive, especially when they persist.
- Most of the time, excessive amounts of deliquescence can lead to elevated absorption of moisture that increases the stress of materials.
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