Nh3 has a greater affinity for protons and ph3 why
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The size of N atom is less than the size of P atom. So the electron density on N atom is more than that on P atom.Hence it becomes a stronger base i.e. it extracts H+ easily which make it have a higher proton affinity than PH3. ... Thus NH3 has more proton affinity than PH3.
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nh3 has great electronegativity and the size is small this increase the nuclear charge of the atom and it attracts electrons towards it
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