nitrobenzene to benzamide
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Nitrobenzene can be converted into benzoic acid as follows. Benzene diazonium chloride is treated with H₃PO₂ to give benzene. Benzene is reacted with CO and HCl in presence of anhydrous AlCl₃ to form benzene. Benzaldehyde is oxidised by acidified KMnO₄ to form benzoic acid.
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Nitrobenzene can be converted to benzamide by following steps -
(i) React Nitrobenzene with H / Pd in presence of ethanol to form aniline .
(ii) Using diazotization reaction , convert aniline into diazonium salt .
(iii) React benzenediazonium chloride with CuCN / KCN then after reacting with HO
ion it will convert into benezoic acid .
(iii) After reacting benezoic acid with SOCl followed by NH
, we get Benzamide .
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