Number of 90 degree interaction between bond pairs in PCl5
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PCl5 has Trigonal bipyramidal Geometry
In the example with the axial lone pair of electrons, when they say, "90 degree to three other electron domains", they just mean that the axial lone pair is situated 90° relative to 3 other substituent bonds - the 3 equatorial substituent bonds in this case. When the lone pair is located in an equatorial position, then it has a 90° interaction with only 2 other bonds .
i hope it will help you
regards
In the example with the axial lone pair of electrons, when they say, "90 degree to three other electron domains", they just mean that the axial lone pair is situated 90° relative to 3 other substituent bonds - the 3 equatorial substituent bonds in this case. When the lone pair is located in an equatorial position, then it has a 90° interaction with only 2 other bonds .
i hope it will help you
regards
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