Order of reactivity of halogen acids in the formation of alkyl halide from ether is
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Carbon - oxygen bond in ethers can be cleaved by halogen acids, sulphuric acid, phosphorouspentachloride etc. The cleavage of C−O bond takes place under drastic conditions with excess of hydrogen halide, R−O−R+2HX→HX→2RX+H 2 O.
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In case of unsymmetrical ethers, the site of cleavage is such that the halide is formed from the alkyl group which is tertiary, so that the halide formed is tertiary halide. ... The order of hydrogen halide reactivity is HI<HBr<HCl.
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