Penta hydrogenphisphate doesnot exist but phosphate pentachloride does why
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PH₅ does not exist but PCl₅ exists, because H is a +I (donating) group and hence, it has very less amount of energy to mix/ hybridise the orbitals and does not significantly pull the electrons
But Cl is more electronegative than P and hence, pulls the electrons significantly and hence hybridises the orbitals easily
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