pH of a solution containing 0.3 M HX and 0.1M X–
(Kb for X– = 1.0 × 10⁻⁵) is –
(a) 5 + log 3(b) 5 – log 3 (c) 9 – log 3(d) 9 + log 3
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(b) 5 – log 3
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Answer:
5 - log 3 is the pH of the solution.
Explanation:
- This question will be solved by Henderson Hasselbach equation
- pKa is equal to -logKb ⇒ - log(1 × 10⁻⁵) ⇒ 5
- log₁₀ [0.1]/[0.3] ⇒ log₁₀ [1/3] ⇒ -log₁₀(3)
- Assembling values in the equation we get
- pH = 5 - log 3
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