Phenylmagnesium chloride reacts with co2 in acidic medium to give
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After addition of acid, an alcohol is obtained. Grignard reagents also add to carbon dioxide (CO2) to form carboxylates, in a reaction similar to their reactions with ketones and aldehydes. This means that instead of adding to the carbonyl, they react with the proton instead and form the carboxylate salt.
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Acid chloride react with excess grignard reagent and give tertiary alcohols. phenyl magnesium bromide, CO2 and water reaction.
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