please guys answer it . Why sulphur has variable valencies?
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There are four atomic orbitals namely s,p,d and f and electrons are distributed
among these orbitals only. Sulphur comes in 3rd period of periodic table and it
contains s,p and d orbital only.
In the ground state, the d orbital remains empty, when excitation occurs there
is jumping of paired electrons to the d orbital and therefore they show an
increase in valency or variable valency.
For example :
In SO2, valency of sulphur is 4, while in SOCl2it is 6.
among these orbitals only. Sulphur comes in 3rd period of periodic table and it
contains s,p and d orbital only.
In the ground state, the d orbital remains empty, when excitation occurs there
is jumping of paired electrons to the d orbital and therefore they show an
increase in valency or variable valency.
For example :
In SO2, valency of sulphur is 4, while in SOCl2it is 6.
nivedhini2004:
thank you so much...
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