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We know, oxidation state of Na+ ion is +1 and oxidation state of Mg2+ ion is +2
so, when NaCl is doped with MgCl2, each Mg2+ ion replace two Na+ ions to maintain electrical neutrality.
here, one site is occurred by Mg2+ ion while the other remains vacent.
Thus, cation vacancies are occurred in Crystal.
therefore , crystal produced impurity detect.
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